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          首页» 课题组» 应用化学» 沈兴海
           

          沈兴海博士,教授(博士生导师)

          专业:应用化学
          研究方向:超分子化学与材料



          电话:010-62765915
          传真:010-62759191
          电子邮箱:xshen@pku.edu.cn

           

          个人简历

          1986,1989,1993年获北京大学理学学士、硕士和博士学位
          1993年,北京大学讲师
          1995年,北京大学副教授
          1996-1997年,加拿大蒙特利尔大学化学系博士后
          1999-2000年,法国Louis Pasteur大学Lehn实验室访问教授
          2000年,北京大学教授
          2001年,北京大学博士生导师

          学术荣誉

          1999年获英国皇家化学会国际作者基金奖励
          2005年入选教育部“新世纪优秀人才支持计划”
          2008年被北京市人民政府聘为特约教育督导(督学)
          2010年当选为中国化学会第二十八届理事会理事

          主讲课程:

          超分子化学、核燃料循环化学

          研究领域与兴趣

          超分子化学基础研究
          1. 环糊精纳米管、环糊精新型包合物、轮烷、分子传感器等超分子体系的设计合成、结构表征和物化性质研究。
          2. 超分子光物理、光化学及量热学研究。
          3. W/O微乳液、离子液体微乳液的结构特征和基本物化性质研究。

            超分子体系在核化学领域的应用基础研究
          4. 超分子体系在核燃料化学领域的应用(离子液体、离子印迹聚合物、浊点萃取等核素分离新方法、新技术研究;微乳液在萃取分离体系中的应用研究)。
          5. 超分子体系中纳米粒子的γ-辐射合成及新的调控方法。 

          代表性论文

          1. Fu, J.; Yang, I. Y.; Zhang, J.; Chen, Q. D.; Shen, X. H.*;Gao, Y. Q.* “Structural Characteristics of Homogeneous Hydrophobic Ionic Liquid?HNO3?H2O Ternary System: Experimental Studies and Molecular Dynamics Simulations” J. Phys. Chem. B,2016, DOI: 10.1021/acs.jpcb.6b01214.
          2. Fu, J.; Chen, Q. D.; Shen X. H.* “Stripping of uranium from an ionic liquid medium by TOPO modified supercritical carbon dioxide” Sci China-Chem2015, 58, 545.
          3. Shi, J. F.; Shen, X. H.* “Construction of Supramolecular Self-Assemblies Based on the Biamphiphilic Ionic Liquid?β-Cyclodextrin System” J. Phys. Chem. B,2014, 118, 1685.
          4. Gao, S.; Sun, T. X.; Chen, Q. D.; Shen, X. H.* “Improvement of the Cloud Point Extraction of Uranyl Ions by the Addition of Ionic Liquids” J. Hazard. Mater., 2013, 263, 562.
          5. Fu, J.; Chen, Q. D.; Sun, T. X; Shen, X. H.* “Extraction of Th(IV) from Aqueous Solution by Room-Temperature Ionic Liquids and Coupled with Supercritical Carbon Dioxide Stripping” Sep. Purif. Technol., 2013, 119, 66.
          6. Zhang, J. J.; Shen, X. H.* “Temperature-induced reversible transition between vesicle and supramolecular hydrogel in the aqueous ionic liquid-β-cyclodextrin system” J. Phys. Chem. B,2013, 117, 1451.
          7. Sun, T. X.; Wang, Z. M.; Shen, X. H.* “Crystallization of cesium complex containing bis(2-propyloxy)calix[4]crown-6 and bis[(trifluoromethyl)s, ulfonyl]imide” Inorg. Chim. Acta,2012, 390, 8.
          8. He, Y. F.; Shen, X. H.*; Chen, Q. D.; Gao, H. C. “Characterization and Mechanism Study of Micrometer-sized Secondary Assembly of β-Cyclodextrin” Phys. Chem. Chem. Phys.2011, 13, 447.
          9. Chen, Q. D.; Shen, X. H.* “Formation of Mesoporous BaSO4 Microspheres with a Larger Pore Size via Ostwald Ripening at Room Temperature” Cryst. Growth Des.2010, 10, 3838.
          10. Chen, Q. D.; Shen, X. H.*; Gao, H. C. “Radiolytic Syntheses of Nanoparticles in Supramolecular Assemblies”Adv. Colloid Interface Sci. 2010, 159, 32.
          11. Xu, C.; Yuan, L. Y.; Shen, X. H.*; Zhai, M. L.* “Efficient removal of caesium ions from aqueous solution using a calix crown ether in ionic liquids: mechanism and radiation effect” Dalton Trans. 2010, 39, 3897.
          12. Xu, C.; Shen, X. H.*; Chen, Q. D.; Gao, H. C. “Investigation on the extraction of Sr2+ from aqueous phase using crown ether-ionic liquid systems” Sci. China Ser. B-Chem. 2009, 52, 1858.
          13. He, Y. F.; Chen, Q. D.; Xu, C.; Zhang, J. J.; Shen, X. H.* “Interaction between Ionic Liquids and β-cyclodextrin: A Discussion of Association Pattern” J. Phys. Chem. B.2009, 113, 231.
          14. He, Y. F.; Fu, P.; Shen, X. H.*; Gao, H. C. “Cyclodextrin-based aggregates” Micron2008, 39, 495. (Invited review article)
          15. Chen, Q. D.; Shen, X. H.*; Gao, H. C. “Formation of Solid and Hollow Cuprous Oxide Nanocubes in Water-in-oil Microemulsions Controlled by the Yield of Hydrated Electron” J. Colloid Interface Sci.2007, 312, 272.
          16. Chen, Q. D.; Shen, X. H.*; Gao, H. C. “Formation of Nanoparticles in Water-in-oil Microemulsions Controlled by the Yield of Hydrated Electron. The Controlled Reduction of Cu2+” J. Colloid Interface Sci.2007, 308, 491.
          17. Wu, A. H.; Shen, X. H.*; Gao, H. C. “Investigation on photophysical properties of a substituted 3H-indole-modified β-cyclodextrin. (II) Efficient photoinduced energy transfer with naphthalene and its derivatives” J. Photochem. Photobiol. A: Chem.2007, 185, 144.
          18. Wu, A. H.; Chen, Q.; Xia, K.; Hou, T. J.; Shen, X. H.*; Gao, H. C.; Xu, X. J. “Investigation on photophysical properties of a substituted 3H-indole-modified β-cyclodextrin (I) Conformation in water and recognition mechanism as a chemosensor” J. Photochem. Photobiol. A: Chem. 2006, 182, 174.
          19. Wu, A. H.; Shen, X. H.*; He, Y. K. “Micrometer-sized rodlike structure formed by the secondary assembly of cyclodextrin nanotube” J. Colloid Interface Sci. 2006, 302, 87.
          20. He, P.; Shen, X. H.*; Gao, H. C. “Size-controlled preparation of Cu2O octahedron nanocrystals and studies on their optical absorption” J. Colloid Interface Sci.2005, 284, 510.

           

          如要了解更多信息,请访问 超分子化学与材料研究室主页


          欢迎对本学术组研究工作感兴趣的本科生、研究生和博士后加入本学术组。

          (2016年6月更新)

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